J/ApJ/758/45        Isotopic Sr abundances in meteorites        (Moynier+, 2012)

Planetary-scale strontium isotopic heterogeneity and the age of volatile depletion of early solar system materials. Moynier F., Day J.M.D., Okui W., Yokoyama T., Bouvier A., Walker R.J., Podosek F.A. <Astrophys. J., 758, 45 (2012)> =2012ApJ...758...45M 2012ApJ...758...45M
ADC_Keywords: Abundances ; Solar system Keywords: astrochemistry; meteorites, meteors, meteoroids; primordial nucleosynthesis Abstract: Isotopic anomalies in planetary materials reflect both early solar nebular heterogeneity inherited from presolar stellar sources and processes that generated non-mass-dependent isotopic fractionations. The characterization of isotopic variations in heavy elements among early solar system materials yields important insight into the stellar environment and formation of the solar system, and about initial isotopic ratios relevant to long-term chronological applications. One such heavy element, strontium, is a central element in the geosciences due to wide application of the long-lived 87Rb-87Sr radioactive as a chronometer. We show that the stable isotopes of Sr were heterogeneously distributed at both the mineral scale and the planetary scale in the early solar system, and also that the Sr isotopic heterogeneities correlate with mass-independent oxygen isotope variations, with only CI chondrites plotting outside of this correlation. The correlation implies that most solar system material formed by mixing of at least two isotopically distinct components: a CV-chondrite-like component and an O-chondrite-like component, and possibly a distinct CI-chondrite-like component. The heterogeneous distribution of Sr isotopes may indicate that variations in initial 87Sr/86Sr of early solar system materials reflect isotopic heterogeneity instead of having chronological significance, as interpreted previously. For example, given the differences in 84Sr/86Sr between calcium aluminum inclusions and eucrites (εg84Sr>2), the difference in age between these materials would be ∼6 Ma shorter than previously interpreted, placing the Sr chronology in agreement with other long- and short-lived isotope systems, such as U-Pb and Mn-Cr. Description: We report new high-precision Strontium isotope data obtained for unspiked samples using a static measurement routine on two ThermoFisher Triton TIMS instruments at the University of Maryland (UMD) and Tokyo Institute of Technology (TT). File Summary: -------------------------------------------------------------------------------- FileName Lrecl Records Explanations -------------------------------------------------------------------------------- ReadMe 80 . This file table1.dat 45 145 Strontium isotopic abundance ratios table2.dat 101 36 Strontium isotopic composition of terrestrial samples and meteorites -------------------------------------------------------------------------------- See also: J/ApJ/748/L25 : Li-Be-B measurements using SIMS (Wielandt+, 2012) J/ApJ/743/L23 : 48Ca heterogeneity in differentiated meteorites (Chen+, 2011) Byte-by-byte Description of file: table1.dat -------------------------------------------------------------------------------- Bytes Format Units Label Explanations -------------------------------------------------------------------------------- 1- 13 A13 --- Sample Sample name 15 I1 --- S [1/3] Session number 17- 21 A5 --- Loc Location (Tokyo or UMD=University of Maryland) 23- 33 F11.9 --- 87Sr/86Sr [0.69/0.77] The 87Sr to 86Sr isotopic abundance 35- 45 F11.9 --- 84Sr/86Sr [0.0564/0.0565] The 84Sr to 86Sr isotopic abundance -------------------------------------------------------------------------------- Byte-by-byte Description of file: table2.dat -------------------------------------------------------------------------------- Bytes Format Units Label Explanations -------------------------------------------------------------------------------- 1- 42 A42 --- Group Meteorite group (1) 44- 60 A17 --- Sample Sample name 62- 81 A20 --- Type Chondrite type 83- 88 A6 --- Loc Place of analysis (TT=Tokyo Tech, or UMD=University of Maryland) 90- 94 F5.2 --- e84Sr [-0.5/2.1] ε84Sr value (3) 96- 99 F4.2 --- e_e84Sr [0.04/0.8] Standard Error (2xSE) 101 I1 --- N [1/7]? Number of replicated measurements -------------------------------------------------------------------------------- Note (1): Weighted average of e84Sr for each meteorite group is highlited in this column by the indication in parenthesis. Note (3): ε = part per 10000 deviations from the terrestrial value. ε84Sr=[(84Sr/86Sr)samples/(84Sr/86Sr)SRM-987-1]x10000. 84Sr/86Sr is normalized to 88Sr/86Sr=8.375209. -------------------------------------------------------------------------------- History: From electronic version of the journal
(End) Greg Schwarz [AAS], Emmanuelle Perret [CDS] 03-Jul-2014
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