J/ApJ/783/L5 Ro-vibration transitions of the protonated argon ion (Cueto+, 2014)

New accurate measurement of 36ArH+ and 38ArH+ ro-vibrational transitions by high resolution IR absorption spectroscopy. Cueto M., Cernicharo J., Barlow M.J., Swinyard B.M., Herrero V.J., Tanarro I., Domenech J.L. <Astrophys. J., 783, L5 (2014)> =2014ApJ...783L...5C 2014ApJ...783L...5C (SIMBAD/NED BibCode)
ADC_Keywords: Atomic physics Keywords: ISM: molecules - methods: laboratory: molecular - molecular data - techniques: spectroscopic Abstract: The protonated argon ion, 36ArH+, was recently identified in the Crab Nebula from Herschel spectra. Given the atmospheric opacity at the frequency of its J=1-0 and J=2-1 rotational transitions (617.5 and 1234.6GHz, respectively), and the current lack of appropriate space observatories after the recent end of the Herschel mission, future studies on this molecule will rely on mid-infrared observations. We report on accurate wavenumber measurements of 36ArH+ and 38ArH+ rotation-vibration transitions in the v=1-0 band in the range 4.1-3.7µm (2450-2715/cm). The wavenumbers of the R(0) transitions of the v=1-0 band are 2612.50135±0.00033 and 2610.70177±0.00042/cm(±3σ) for 36ArH+ and 38ArH+, respectively. The calculated opacity for a gas thermalized at a temperature of 100K and with a linewidth of 1km/s of the R(0) line is 1.6x10-15xN(36ArH+). For column densities of 36ArH+ larger than 1x1013/cm2, significant absorption by the R(0) line can be expected against bright mid-IR sources. Description: We did accurate laboratory measurement of 19 lines of the v=1-0 band of 36ArH+ and 38ArH+. The new wavenumbers have improved the Dunham-type fit to all published rotation and vibration-rotation data for all isotopologues of this molecule, allowing more accurate predictions of other transitions for any of them. Table3 contains all published observed frequencies of all isotopologues, as well as the values calculated from our fit. File Summary: -------------------------------------------------------------------------------- FileName Lrecl Records Explanations -------------------------------------------------------------------------------- ReadMe 80 . This file table3.dat 88 367 Measured and calculated ro-vibrational transitions of the isotopologues of ArH+ -------------------------------------------------------------------------------- See also: J/ApJ/799/115 : Absorption spectrum of SO up to 2.5THz (Martin-Drumel+, 2015) Byte-by-byte Description of file: table3.dat -------------------------------------------------------------------------------- Bytes Format Units Label Explanations -------------------------------------------------------------------------------- 1- 10 A10 --- Iso Isotopologue (36ArD+, 36ArH+, 38ArD+, 38ArH+, 40ArD+, or 40ArH+) 12- 13 I2 --- J' [0/36] Upper level J quantum number Ju 15- 16 I2 --- J" [0/35] Lower level J quantum number Jl 18 I1 --- v' [0/7] Upper level vibrational state vu 20 I1 --- v" [0/6] Lower level vibrational state vl 22- 27 A6 --- x_Freq1 Frequency units (MHz or cm-1) (1) 29- 41 F13.4 --- Freq1 [404/1.33e+07] Observed frequency νobs 43- 50 F8.5 --- e_Freq1 [0/50] The 1σ uncertainty in Freq1 (2) 52- 66 F15.6 --- Freq2 [404/1.3311e+07] Predicted frequency νcal 68- 75 F8.6 --- e_Freq2 [2e-05/6.6] The 1σ uncertainty in Freq2 77- 86 F10.6 --- O-C [-54/30] The νobscal difference 88 I1 --- Ref [1/9] Reference code (3) -------------------------------------------------------------------------------- Note (1): These units apply to all the elements of each row. Note (2): Transitions with e_Freq1=0 have been discarded in the fit due to a large O-C value. Note (3): Reference code defined as follows: 1 = This work; 2 = Filgueira & Blom (1988JMoSp.127..279F 1988JMoSp.127..279F); 3 = Bowman et al. (1983JChPh..79.2093B 1983JChPh..79.2093B); 4 = Brown et al. (1988JMoSp.128..587B 1988JMoSp.128..587B); 5 = Liu et al. (1987JChPh..87.2442L 1987JChPh..87.2442L); 6 = Brault & Davis (1982PhyS...25..268B 1982PhyS...25..268B); 7 = Johns (1984JMoSp.106..124J 1984JMoSp.106..124J); 8 = Laughlin et al. (1988RSPTA.324..109L 1988RSPTA.324..109L); 9 = Odashima et al. (1999JMoSp.195..356O 1999JMoSp.195..356O). -------------------------------------------------------------------------------- History: From electronic version of the journal
(End) Prepared by [AAS]; Sylvain Guehenneux [CDS] 15-Apr-2016
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