J/ApJS/158/188    Detection of glycolaldehyde toward Sgr B2     (Widicus+, 2005)

Millimeter-wave and vibrational state assignments for the rotational spectrum of glycolaldehyde. Widicus Weaver S.L., Butler R.A.H., Drouin B.J., Petkie D.T., Dyl K.A., De Lucia F.C., Blake G.A. <Astrophys. J. Suppl. Ser., 158, 188-192 (2005)> =2005ApJS..158..188W 2005ApJS..158..188W
ADC_Keywords: Interstellar medium ; Spectra, millimetric/submm Keywords: ISM: molecules - methods: data analysis - methods: laboratory - molecular data - radio lines: ISM Abstract: Glycolaldehyde (CHOCH2OH), the simplest two-carbon α-hydroxy aldehyde, has become of great interest in the field of astrochemistry due to its recent detection toward the Sagittarius B2 (N-LMH) molecular cloud. The original interstellar identification was based on an extrapolation of prior microwave rotational spectroscopy of glycolaldehyde. The millimeter and submillimeter spectra of this molecule from 128 to 354GHz were subsequently measured after the interstellar detection. We present here the millimeter spectrum of this molecule from 72 to 122.5GHz along with a combined millimeter and submillimeter pure rotational analysis of the ground and the first three vibrationally excited states of glycolaldehyde that enables a more complete molecular partition function to be determined. Description: The millimeter and submillimeter spectra of glycolaldehyde from 128 to 354GHz were obtained with the Fast Scanning Submillimeter Spectroscopic Technique (FASSST) system at the Ohio State University. Additional millimeter studies from 72 to 122.5GHz were conducted with the millimeter and submillimeter spectrometer at the Jet Propulsion Laboratory. Objects: ---------------------------------------------------------- RA (2000) DE Designation(s) ---------------------------------------------------------- 17 47 20.4 -28 23 07 Sagittarius B2 = SNR 000.7+00.0 ---------------------------------------------------------- File Summary: -------------------------------------------------------------------------------- FileName Lrecl Records Explanations -------------------------------------------------------------------------------- ReadMe 80 . This file table1.dat 84 3160 Assigned transitions for the ground and first three vibrationally excited states of glycolaldehyde -------------------------------------------------------------------------------- See also: J/ApJS/117/427 : Sgr B2 spectral survey (Nummelin+, 1998) Byte-by-byte Description of file: table1.dat -------------------------------------------------------------------------------- Bytes Format Units Label Explanations -------------------------------------------------------------------------------- 1- 2 I2 --- J' The upper J quantum number 5- 6 I2 --- Ka' The upper Ka quantum number 9- 10 I2 --- Kc' The upper Kc quantum number 13- 14 I2 --- v' The upper v quantum number 17- 18 I2 --- J" The lower J quantum number 21- 22 I2 --- Ka" The lower Ka quantum number 25- 26 I2 --- Kc" The lower Kc quantum number 29- 30 I2 --- v" The lower v quantum number 45- 56 F12.5 MHz Freq The frequency of the transition 62- 69 F8.5 MHz O-C The observed minus calculated value 74- 80 F7.5 MHz e_O-C The experimental uncertainty in O-C 84 A1 --- Blend [B] Signifies blend (1) -------------------------------------------------------------------------------- Note (1): A "B" marks components of an unresolved blend of lines with different quantum numbers. -------------------------------------------------------------------------------- History: From electronic version of the journal
(End) Greg Schwarz [AAS], Marianne Brouty [CDS] 07-Dec-2005
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