33 (Fig. 1.8) has a peculiar spectrum, which was classified as O9.7 Iabpe. It 33 presents emission at H{gamma} and all the lines appear peculiarly weak for 33 a supergiant star. 35 (Fig. 1.9) is a widely studied object because it is the optical counterpart 35 to the X-ray source LMC X-1. Hutchings et al. (1983ApJ...275L..43H) found 35 it to be an O7 star with a binary period of approximately 4 days; they 35 also suggested that the secondary could be a black hole. It was later 35 classified as O7-9 III by Pakull (1984, IAU Symp., 108, 317) and 35 Bianchi & Pakull (1985A&A...146..242B). We find a type of O8(f)p, where the 35 peculiarity refers to the reversed HeII {lambda}4686 emission. For this 35 reason it has been associated with the Onfp class by N.R. Walborn et al. 35 (2009, in preparation), of which the HeII profile is a defining 35 characteristic, 35 although in this object the absorption lines are not 35 broadened, and the HeII profile may be related to the X-ray binary system. 37 (Fig. 1.4) was classified as O8 here, although Conti & Fitzpatrick 37 (1991ApJ...373..100C) classified it as O3-O6, based on the presence of 37 HeII {lambda}{lambda}4200, 4541, 4686 absorption lines and possible 37 NIII {lambda}{lambda}4634-40-42 emission lines. The stellar HeI absorption 37 lines were obliterated by the very strong nebular emission lines in their 37 observation. For our classification we used mainly the ratios of 37 HeII {lambda}4541/HeI {lambda}4387 and HeII {lambda}4200/HeI {lambda}4144. 37 We also used the oversubtracted nebular [OIII] {lambda}4363 line present 37 in the final spectrum to estimate the nebular oversubtraction (see Bosch 37 et al. 1999A&AS..137...21B). We found a correction of less than 15%, 37 which indicates that the stellar HeI {lambda}4471 absorption is indeed 37 deeper than HeII {lambda}4541. In addition, the CIII {lambda}4070 37 absorption blend is present. All of these considerations indicate that the 37 spectral type of Star 37 must be closer to O8. Unfortunately, our 37 wavelength coverage for this object did not allow us to check for the 37 presence of NIII emission, as suspected by Conti & Fitzpatrick 37 (1991ApJ...373..100C). The luminosity class could not be assessed due 37 to the lack of the HeII {lambda}4686 line. 38 (Fig. 1.17) is a B3 supergiant that at one time was also a candidate for 38 identification with LMC X-1. Fortunately, the weak HeII {lambda}4686 38 emission seen in high S/N digital data was not visible in the early 38 observations, or this misidentification would have been considered 38 definite! Ramsey et al. (2006ApJ...641..241R) have clearly shown that this 38 anomalous emission feature actually arises in an unusual high-ionization 38 nebulosity in the field, which may be related to the X-ray source. 39 (Fig. 1.8) was classified as O9.7 Ia+pe. It is certainly an unusual 39 spectrum, probably related to the Ofpe/WN9 or WNL class. See, for 39 comparison, the spectrum of HD 152408 (Walborn et al. 2000PASP..112...50W). 39 However, these characteristics have not been seen before at such a late 39 O type. 41 (Fig. 1.1) is the hottest star we have found among the sample. It was 41 classified as O3 Vz((f*)), although the z nature (HeII {lambda}4686 41 absorption stronger than other He lines, possibly an indicator of 41 subluminosity and extreme youth) is marginal. 41 NIII {lambda}{lambda}4634-40-42 and NIV {lambda}4058 are clearly detected 41 in emission and NV {lambda}{lambda}4604-20 absorption lines are also 41 present. SiIV {lambda}{lambda}4089-4116 seem to be in emission but the 41 features are not conspicuous. 93 (Fig. 1.10) was classified as BN0 Iabp due to enhanced NIII and deficient 93 C and O lines, characteristic of OBN stars (Walborn 1971ApJ...164L..67W, 93 1976ApJ...205..419W). The additional peculiarity is the presence of P Cygni 93 profiles at H{gamma} and HeI lines. 179 (Fig. 1.10) was classified as B Iae P Cyg. The P Cygni features can be seen 179 in H{epsilon} and H{delta}, but not in H{gamma} which is totally in 179 emission. This object is quite similar to HD 87643 (Walborn & Fitzpatrick 179 2000PASP..112...50W), which belongs to the group of Iron Stars, of which 179 {eta} Carinae is the most famous member. 54 54, 70, 76, 107, and 112 (Fig. 1.20) show either anomalously broad or 54 asymmetric profiles in their absorption lines, suggesting a possible 54 binary nature. The wavelength resolution does not allow us to reliably 54 analyze radial velocity information. Higher resolution spectra would be 54 needed to assess the possibility of these being SB2 stars. 70 54, 70, 76, 107, and 112 (Fig. 1.20) show either anomalously broad or 70 asymmetric profiles in their absorption lines, suggesting a possible 70 binary nature. The wavelength resolution does not allow us to reliably 70 analyze radial velocity information. Higher resolution spectra would be 70 needed to assess the possibility of these being SB2 stars. 76 54, 70, 76, 107, and 112 (Fig. 1.20) show either anomalously broad or 76 asymmetric profiles in their absorption lines, suggesting a possible 76 binary nature. The wavelength resolution does not allow us to reliably 76 analyze radial velocity information. Higher resolution spectra would be 76 needed to assess the possibility of these being SB2 stars. 107 54, 70, 76, 107, and 112 (Fig. 1.20) show either anomalously broad or 107 asymmetric profiles in their absorption lines, suggesting a possible 107 binary nature. The wavelength resolution does not allow us to reliably 107 analyze radial velocity information. Higher resolution spectra would be 107 needed to assess the possibility of these being SB2 stars. 112 54, 70, 76, 107, and 112 (Fig. 1.20) show either anomalously broad or 112 asymmetric profiles in their absorption lines, suggesting a possible 112 binary nature. The wavelength resolution does not allow us to reliably 112 analyze radial velocity information. Higher resolution spectra would be 112 needed to assess the possibility of these being SB2 stars. 72 72, 82, and 151 (Fig. 1.9) belong to the Onfp category (Walborn 72 1973AJ.....78.1067W). In their spectra, the broad emission in 72 HeII {lambda}4686 with absorption reversal can be observed (see the 72 Appendix). 82 72, 82, and 151 (Fig. 1.9) belong to the Onfp category (Walborn 82 1973AJ.....78.1067W). In their spectra, the broad emission in 82 HeII {lambda}4686 with absorption reversal can be observed (see the 82 Appendix). Stars 72 and 82 are also denoted with "+" due to 82 SiIV {lambda}4116 emission; they also present CIII {lambda}4650 in 82 emission. A luminosity class cannot be inferred for these stars because 82 of the peculiar HeII {lambda}4686 profiles (N.R. Walborn et al. 2009, 82 in preparation). 151 72, 82, and 151 (Fig. 1.9) belong to the Onfp category (Walborn 151 1973AJ.....78.1067W). In their spectra, the broad emission in 151 HeII {lambda}4686 with absorption reversal can be observed (see the 151 Appendix). Stars 72 and 82 are also denoted with "+" due to 151 SiIV {lambda}4116 emission; they also present CIII {lambda}4650 in 151 emission. A luminosity class cannot be inferred for these stars because 151 of the peculiar HeII {lambda}4686 profiles (N.R. Walborn et al. 2009, 151 in preparation).