HD168625 is an evolved luminous early-type supergiant (Mbol=-8.6), recently found to be surrounded by a dusty nebula most probably ejected by the star (Hutsemekers et al. 1994). It is related to the rare Luminous Blue Variable stars (LBVs), which constitute an important stage in the evolution of the very massive stars. Since these stars are expected to eject material enriched in nitrogen at the expense of carbon, the presence in the spectrum of HD168625 of Unidentified Infrared emission features at 6.2, 6.9, and 7.7 micron (UIRs), generally associated with carbon-rich objects (Cohen et al. 1986), is puzzling and unique among LBVs and related stars. We propose here to carry out a detailed study of the circumstellar environment of HD168625, i.e. 1. to locate the origin of the UIR emission features using ISO CAM, 2. to derive the C, N, O abundances in the outer wind + nebula using the far-infrared fine structure emission lines observable with ISO LWS. For comparison, we also propose to derive the C, N, O abundances for the nearby LBV HD168607, which is of comparable luminosity and spectral type, but which is not associated with a nebula. These data will provide us with important information on the evolutionary status and mass-loss history of both stars, as well as on dust formation processes. These data will supplement with a particularly interesting object the other LBV observations foreseen by different consortia in the framework of the Guaranteed Time programme.