3_1 One of the two optical counterparts of this source has been identified as 3_1 a variable star. More details of source 3_1 are presented in Section A.4. 3_4 A single optical match was identified in both OGLE-II and MCPS catalogs. 3_4 However, its V=18.19 magnitude and B-V=0.37 color are not indicative of 3_4 the nature of the companion star. Its soft X-ray spectrum (A. Zezas et al. 3_4 2009, in preparation) possibly suggests an AGN. 5_9 Chandra sources 5_9 and 6_8 have possibly a soft X-ray spectrum and 5_9 multiple optical matches within their search radius. The brightest matches 5_9 of 5_9 and 6_8 are not O or B-type stars (B-V color~0.59 and ~1.12mag, 5_9 respectively). Recently, Laycock et al. (2010ApJ...716.1217L) detected 5_9 source 5_9 as a candidate quiescent X-ray pulsar (SXP7.83). 6_8 Chandra sources 5_9 and 6_8 have possibly a soft X-ray spectrum and 6_8 multiple optical matches within their search radius. The brightest matches 6_8 of 5_9 and 6_8 are not O or B-type stars (B-V color~0.59 and ~1.12mag, 6_8 respectively). 5_15 Within the search radius of this source we identified five matches, all of 5_15 them fainter than V~19mag. Its possibly soft X-ray spectrum suggests an 5_15 AGN. However, Laycock et al. (2010ApJ...716.1217L) detected this source as 5_15 a candidate quiescent X-ray pulsar, while the brightest of its matches has 5_15 been identified as a Be candidate star (Mennickent et al. 5_15 2002A&A...393..887M). See also the discussion in Section 9. 5_23 We identify MCPS source Z_2288276 (no OGLE-II overlap) as the optical 5_23 counterpart of X-ray source 5_23. Based on its V magnitude and B-V color, 5_23 this is an O or B-type star. Thus, we classify this source as a new 5_23 candidate HMXB. The small number of net counts of source 5_23 (~10 counts 5_23 in the 0.5-7.0keV energy band; A. Zezas et al. 2009, in preparation) does 5_23 not allow us to derive its X-ray spectral information, thus prohibiting us 5_23 to classify it further as a new candidate Be-XRB. 4_10 Chandra sources 4_10, 5_6, 5_32, 6_3, 7_17: The soft X-ray spectrum of 4_10 these sources (HR method, more details in Table 7 and its description in 4_10 Section 8.3) and their early-type counterparts could be indicative of a 4_10 candidate black hole X-ray binary (BH-XRB) nature. However, only X-ray 4_10 spectral fits and optical spectroscopy of the companion stars could 4_10 possibly identify their true nature. 5_6 Chandra sources 4_10, 5_6, 5_32, 6_3, 7_17: The soft X-ray spectrum of 5_6 these sources (HR method, more details in Table 7 and its description in 5_6 Section 8.3) and their early-type counterparts could be indicative of a 5_6 candidate black hole X-ray binary (BH-XRB) nature. However, only X-ray 5_6 spectral fits and optical spectroscopy of the companion stars could 5_6 possibly identify their true nature. 5_32 Chandra sources 4_10, 5_6, 5_32, 6_3, 7_17: The soft X-ray spectrum of 5_32 these sources (HR method, more details in Table 7 and its description in 5_32 Section 8.3) and their early-type counterparts could be indicative of a 5_32 candidate black hole X-ray binary (BH-XRB) nature. However, only X-ray 5_32 spectral fits and optical spectroscopy of the companion stars could 5_32 possibly identify their true nature. 6_3 Chandra sources 4_10, 5_6, 5_32, 6_3, 7_17: The soft X-ray spectrum of 6_3 these sources (HR method, more details in Table 7 and its description in 6_3 Section 8.3) and their early-type counterparts could be indicative of a 6_3 candidate black hole X-ray binary (BH-XRB) nature. However, only X-ray 6_3 spectral fits and optical spectroscopy of the companion stars could 6_3 possibly identify their true nature. 7_17 Chandra sources 4_10, 5_6, 5_32, 6_3, 7_17: The soft X-ray spectrum of 7_17 these sources (HR method, more details in Table 7 and its description in 7_17 Section 8.3) and their early-type counterparts could be indicative of a 7_17 candidate black hole X-ray binary (BH-XRB) nature. However, only X-ray 7_17 spectral fits and optical spectroscopy of the companion stars could 7_17 possibly identify their true nature. 6_20 The small number of net counts of this source (less than 10 counts in the 6_20 0.5-7.0keV energy band; A. Zezas et al. 2009, in preparation) does not 6_20 allow us to derive spectral information for it. Its V=13.71 magnitude and 6_20 B-V=0.39 color are not indicative of the nature of the companion star, 6_20 thus this source remains unclassified in this work. More details on this 6_20 source are presented in Section 3. 7_17 This source has possibly a soft X-ray spectrum. The large search radius of 7_17 it (5.29", maximum search radius used in this study because of the large 7_17 off-axis angle) resulted in the identification of multiple matches. 7_17 However, only two sources are bright (V~18.4 mag, thus resulting in 7_17 smaller chance coincidence probability). One of the two sources lies on 7_17 the red giant branch, while the other one (O_5_140992) falls just outside 7_17 the locus of OB spectral type stars. Source 7_17 remains unclassified in 7_17 this work. 7_19 Due to the small number of counts (less than 10 counts in the 0.5-7.0keV 7_19 energy band; A. Zezas et al. 2009, in preparation) we do not have X-ray 7_19 spectral information for this source. However, there is an emission-line 7_19 object within ~2{sigma} of the search radius (source [MA93]316; 7_19 Meyssonnier & Azzopardi 1993, Cat. J/A+AS/102/451). Actually this source 7_19 is located in the star cluster SMC-N32 (Bica & Schmitt 1995, 7_19 Cat. J/ApJS/101/41), a crowded region surrounded by a diffuse emission 7_19 (HII region). The detection algorithm in this case resulted in many 7_19 spurious sources that they were not deblended (see also the online finding 7_19 chart for this source). We note here that the brightest of the five 7_19 matches within the search radius of this source is located just to the 7_19 right border of the ellipse of OB stars in the V, B-V CMD. Its large error 7_19 in B-V color could place it within the ellipse, thus suggesting that it 7_19 could be another new HMXB. 4_32 Chandra sources 4_32, 4_36, 5_18, 5_25, 6_23, 7_9: All but two of the 4_32 brightest counterparts of these sources lie on the red giant branch in the 4_32 V, B-V CMD (Figure 3), while that of source 5_18 lies on the right of the 4_32 MS (most probably in the giant branch). The counterpart of source 7_9 has 4_32 M_V_0__=-5.7 and (B-V)_0_>0.75, thus it lies on the locus of foreground 4_32 stars (for more details see Section 6). In addition, these sources do not 4_32 have X-ray spectral information (because of their small number of counts), 4_32 except from source 7_9 which has possibly a hard X-ray spectrum. 4_36 Chandra sources 4_32, 4_36, 5_18, 5_25, 6_23, 7_9: All but two of the 4_36 brightest counterparts of these sources lie on the red giant branch in the 4_36 V, B-V CMD (Figure 3), while that of source 5_18 lies on the right of the 4_36 MS (most probably in the giant branch). The counterpart of source 7_9 has 4_36 M_V_0__=-5.7 and (B-V)_0_>0.75, thus it lies on the locus of foreground 4_36 stars (for more details see Section 6). In addition, these sources do not 4_36 have X-ray spectral information (because of their small number of counts), 4_36 except from source 7_9 which has possibly a hard X-ray spectrum. 5_18 Chandra sources 4_32, 4_36, 5_18, 5_25, 6_23, 7_9: All but two of the 5_18 brightest counterparts of these sources lie on the red giant branch in the 5_18 V, B-V CMD (Figure 3), while that of source 5_18 lies on the right of the 5_18 MS (most probably in the giant branch). The counterpart of source 7_9 has 5_18 M_V_0__=-5.7 and (B-V)_0_>0.75, thus it lies on the locus of foreground 5_18 stars (for more details see Section 6). In addition, these sources do not 5_18 have X-ray spectral information (because of their small number of counts), 5_18 except from source 7_9 which has possibly a hard X-ray spectrum. 5_25 Chandra sources 4_32, 4_36, 5_18, 5_25, 6_23, 7_9: All but two of the 5_25 brightest counterparts of these sources lie on the red giant branch in the 5_25 V, B-V CMD (Figure 3), while that of source 5_18 lies on the right of the 5_25 MS (most probably in the giant branch). The counterpart of source 7_9 has 5_25 M_V_0__=-5.7 and (B-V)_0_>0.75, thus it lies on the locus of foreground 5_25 stars (for more details see Section 6). In addition, these sources do not 5_25 have X-ray spectral information (because of their small number of counts), 5_25 except from source 7_9 which has possibly a hard X-ray spectrum. 6_23 Chandra sources 4_32, 4_36, 5_18, 5_25, 6_23, 7_9: All but two of the 6_23 brightest counterparts of these sources lie on the red giant branch in the 6_23 V, B-V CMD (Figure 3), while that of source 5_18 lies on the right of the 6_23 MS (most probably in the giant branch). The counterpart of source 7_9 has 6_23 M_V_0__=-5.7 and (B-V)_0_>0.75, thus it lies on the locus of foreground 6_23 stars (for more details see Section 6). In addition, these sources do not 6_23 have X-ray spectral information (because of their small number of counts), 6_23 except from source 7_9 which has possibly a hard X-ray spectrum. 7_9 Chandra sources 4_32, 4_36, 5_18, 5_25, 6_23, 7_9: All but two of the 7_9 brightest counterparts of these sources lie on the red giant branch in the 7_9 V, B-V CMD (Figure 3), while that of source 5_18 lies on the right of the 7_9 MS (most probably in the giant branch). The counterpart of source 7_9 has 7_9 M_V_0__=-5.7 and (B-V)_0_>0.75, thus it lies on the locus of foreground 7_9 stars (for more details see Section 6). In addition, these sources do not 7_9 have X-ray spectral information (because of their small number of counts), 7_9 except from source 7_9 which has possibly a hard X-ray spectrum. 4_16 This is a point source associated with the previously known SNR 0047-735 4_16 (Mathewson et al. 1984ApJS...55..189M). For this source, one single 4_16 optical match (O_5_27768) has been found, while it has been recently 4_16 classified as a new candidate quiescent X-ray pulsar (CXO J004905.1-731411 4_16 =SXP8.94; Laycock et al. 2010ApJ...716.1217L). 4_20 This point source is associated with the previously known SNR 0049-73.6 4_20 (Mathewson et al. 1984ApJS...55..189M). We identify source O_5_262679 as 4_20 the optical counterpart of source 4_2. CXO J005059.0-732055 (SXP9.39; 4_20 Laycock et al. 2010ApJ...716.1217L) has been classified as a candidate 4_20 quiescent X-ray pulsar. 4_21 This point source is also associated with the SNR 0049-73.6 (Mathewson et 4_21 al. 1984ApJS...55..189M; Sasaki et al. 2000, Cat. J/A+AS/147/75). There 4_21 are three bright counterparts (M_V_0__<-0.25) within its search radius, 4_21 while one of those (O_5_256826) is an early-type star (O or B). 3_3 The identified counterpart O_8_49531 (single match) of X-ray source 3_3 is 3_3 a Be candidate star ([MPG02]No.494), in agreement with the identification 3_3 of Sasaki et al. (2003A&A...403..901S). 4_2 We find two matches for X-ray source 4_2. Although none of them are located 4_2 within the locus of OB stars (criterion (1)), we identify source 4_2 O_5_111490 as the counterpart for 4_2, because of its Be nature 4_2 ([MPG02]No.206), while it was also found to be a variable star (Ita et al. 4_2 2004, Cat. J/MNRAS/353/705). This is in agreement with the identification 4_2 of Coe et al. (2005MNRAS.356..502C). 4_17 Source O_5_180008 is identified as the optical counterpart of X-ray source 4_17 4_17, while it is also identified as a Be candidate star ([MPG02]No.265). 4_17 This source coincides with the emission-line object [MA93]396. In 4_17 combination with the possibly hard X-ray spectrum, we classify this source 4_17 as a new Be-XRB. 5_3 The identified optical counterpart O_6_85614 (in agreement with Schmidtke & 5_3 Cowley 2006AJ....132..919S) is a Be candidate star [MPG02]No.321. It is of 5_3 B0-5 spectral type (source [2dF]No.0828; see Section 3), and it has been 5_3 found to coincide with the emission-line object [MA93]No.506 (in agreement 5_3 with Haberl & Sasaki 2000A&A...359..573H). 5_7 The identified optical counterpart of X-ray source 5_7 is source O_7_70829. 5_7 It is identified as a Be candidate star ([MPG02]No.426), while Sasaki et 5_7 al. (2003A&A...403..901S) presented the same counterpart, identified also 5_7 as the emission-line object [MA93]No.810. 5_15 We identify source O_7_71429 as the optical counterpart of X-ray source 5_15 5_15 (see also Section 9). This is also reported as a Be candidate star 5_15 ([MPG02]No.423). However, Dobrzycki et al. (2003AJ....125.1330D) 5_15 identified this object as a quasar (z=1.79) located behind the SMC (based 5_15 on a spectroscopic study). 6_1 The identified counterpart O_6_77228 of source 6_1 is a candidate Be star 6_1 ([MPG02]No.341; see also Section 3). 6_4 Source O_6_147662 is identified as the optical counterpart of X-ray source 6_4 6_4. This optical source is also reported as a candidate Be star 6_4 ([MPG02]No.364), and it is located ~0.57" away from the emission-line 6_4 object [MA93]618 (in agreement with Haberl & Sasaki 2000A&A...359..573H). 7_1 We identify source O_5_65517 as the optical counterpart of X-ray source 7_1 7_1. This is star 1 of Stevens et al. (1999MNRAS.309..421S), and it is 7_1 also in agreement with the identification of Coe & Orosz 7_1 (2000MNRAS.311..169C). This OGLE source is identified as a Be candidate 7_1 star ([MPG02]No.199). 3_1 We identify source O_7_267163 as the optical counterpart of X-ray source 3_1 3_1. From visual inspection of the finding chart, from comparison of the 3_1 V magnitude for sources O_7_267163 and O_7_267132, and taking into account 3_1 the ~0.7" astrometric accuracy of OGLE, we believe that these stars are a 3_1 single source. Although none of the identified matches are an early-type 3_1 star, and the parameter {xi} cannot distinguish in this case the right 3_1 counterpart, source O_7_267163 is identified as a variable star 3_1 (OGLE00571981-72253375) in the study of Zebrun et al. (2001, 3_1 Cat. J/AcA/51/317). Sasaki et al. (2003A&A...403..901S) identified the 3_1 same object, while they also associated it with star 3_1 USNOA2.0 0150-00625436. The soft X-ray spectrum of 3_1 and the 3_1 identification of the optical counterpart as a background quasar 3_1 (Dobrzycki et al. 2003AJ....126..734D) suggest that this is possibly an 3_1 AGN (in agreement with Sasaki et al. 2003A&A...403..901S). 4_2 Source O_5_111490 is also identified as a variable star in the analysis of 4_2 Ita et al. (2004, Cat. J/MNRAS/353/705; see also Section 9). 4_5 The optical counterpart of X-ray source 4_5 is the variable star O_5_111500 4_5 (single optical match; P_pulse,opt_=89.835days; Ita et al. 2004, 4_5 Cat. J/MNRAS/353/705). Haberl et al. (2008A&A...489..327H) have recently 4_5 confirmed the Be-XRB nature of this source, while no significant 4_5 pulsations have been found in their study. In a later work, Laycock et al. 4_5 (2010ApJ...716.1217L) identified Chandra source 4_5 as the X-ray pulsar 4_5 SXP892. 4_11 Source O_4_164855 is the single match of Chandra source 4_11 within the 4_11 search radius with V magnitude and B-V color which place it just below the 4_11 locus of OB stars in the CMD. We mention here that in ~2{sigma} from the 4_11 X-ray source position there is a bright variable star (O_4_163513= 4_11 OGLE 004802.55-731659.8; Ita et al. 2004, Cat. J/MNRAS/353/705). However, 4_11 the B-V color of this optical source is not indicative of an O or B-type 4_11 star, thus even if its X-ray spectrum is possibly hard this source remains 4_11 unclassified. 5_1 The identified optical counterpart in this case is MCPS source Z_2311496, 5_1 in agreement with Coe et al. (2005MNRAS.356..502C). This source is also 5_1 defined as a B0-5(II)e star in the 2dF spectroscopic catalog of Evans et 5_1 al. (2004, Cat. J/MNRAS/353/601; source [2dF]No.0839). 5_3 The optical counterpart O_6_85614 of source 5_3 is identified as a B0-5(II) 5_3 spectral-type source ([2dF]No.0828). 5_16 A single match (source Z_2573354) is identified as the optical counterpart 5_16 of this source in the MCPS catalog (no OGLE-II overlap), in agreement with 5_16 Coe et al. (2005MNRAS.356..502C). Buckley et al. (2001MNRAS.320..281B) 5_16 identified source 5_16 as a transient pulsar and spectroscopically 5_16 classified the suggested counterpart (star A or B mentioned in their 5_16 study) as a B1-B2III-Ve star. On the other hand, the variable MACHO source 5_16 207.16202.30 lies >14" away of X-ray source 5_16 (unlikely the correct 5_16 counterpart; Coe et al. 2005MNRAS.356..502C). 6_1 We identify source O_6_77228 as the optical counterpart of X-ray source 6_1 6_1 (in agreement with Coe et al. 2005MNRAS.356..502C). This is source 6_1 [2dF]No.5054 classified as a B1-5(II)e star (Evans et al. 2004, 6_1 Cat. J/MNRAS/353/601). It also appears as a candidate Be star in the 6_1 compilation of Mennickent et al. (2002A&A...393..887M; [MPG02]No.341). For 6_1 more details see Section 9. 6_20 Source O_6_311169 (single match) is proposed here as the optical 6_20 counterpart of X-ray source 6_20. It is the brightest counterpart 6_20 identified in this study, while it has been identified as the 6_20 emission-line object [MA93]No.739 (peculiar H{alpha} emission-line star 6_20 with FeII and [FeII] emission; ~0.17" from the OGLE-II source, and ~0.8" 6_20 from the X-ray source). The latter source has been identified as a B[e] 6_20 star by Massey & Duffy (2001ApJ...550..713M). We only propose the above 6_20 OGLE-II source as the counterpart of Chandra source 6_20, and we note that 6_20 further analysis of this peculiar system is required so as to confirm its 6_20 nature (see also Appendix 9). 3_2 This source is a pulsar (Edge et al. 2004MNRAS.353.1286E). However, both of 3_2 its optical matches in the MCPS catalog presented in Table 2 (no overlap 3_2 with OGLE-II) are faint stars. Due to the high chance coincidence 3_2 probability of faint sources, we do not propose any of them as counterpart 3_2 of X-ray source 3_2. Instead, looking for counterparts between the 3_2 1{sigma} and 2{sigma} search radii, we find MCPS source Z_2806702 (in 3_2 agreement with Edge et al. 2004MNRAS.353.1286E). This is a bright star 3_2 (V=16.78, B-V =-0.12), which is located 4.27" away from the X-ray 3_2 position. Although no spectroscopic data for these three sources are 3_2 available, the early-type nature of MCPS source Z_2806702 makes us believe 3_2 that this is the most likely counterpart. Recently, Haberl & Eger 3_2 (2008ATel.1529....1H) suggested that Chandra source 3_2 is a background 3_2 AGN and not a Be-XRB pulsar, with an optical counterpart one of the two 3_2 faint stars with V=20.3mag found in the 1{sigma} search radius. 4_13 We have identified source O_5_90858 as the optical counterpart of 4_13. 4_13 However, when we look for counterparts between the 1{sigma} and 2{sigma} 4_13 search radii, we find two sources brighter than O_5_90858. These sources, 4_13 O_5_90493 and O_5_90535 (5.47" and 4.10" away from the X-ray source, 4_13 respectively), are both of OB spectral type (V=15.57, B-V=-0.07 and 4_13 V=16.34, B-V=0.23, respectively). The possibly hard X-ray spectrum of 4_13 4_13 suggests that this is a new candidate Be-XRB. However, only optical 4_13 spectroscopy could determine the exact type of these bright stars and the 4_13 true counterpart of Chandra source 4_13. 4_19 The optical source O_5_261182 is found 2.27" away from Chandra source 4_19 4_19 (between the 1{sigma} and 2{sigma} search radius), and it is an OB 4_19 spectral-type star (V=18.16, B-V=-0.08). In combination with its possibly 4_19 hard X-ray spectrum, we propose this as a new HMXB. Optical spectroscopy 4_19 will definitely determine if this source is also a new Be-XRB.