As recently discovered, planetary satellites exhibit a diversity of physical phenomena that has opened a new and active field of research. We propose to make a comparative study of three most interesting couples of objects in the outer solar system, i.e. Iapetus and Hyperion; Pluto and Triton; Titania and Oberon using low-resolution spectra of these objects in the 2.5 - 12 microns waveband. Such data have never been obtained because Voyager spacecrafts did not include the adequate instruments and because of the too low angular resolution of I.R.A.S. The present scientific goal is manifold: - a search for spectral signatures from organic and non organic compounds such as CO2, CO, carbonates, silicates, sulfates, etc. to investigate the nature of the dark material in the outer solar system; - a comparative study of these satellites and a comparison with other asteroids and planetary rings material; - a study of the behaviour of ices at low temperature and pressure, far from conditions on Earth; - a better understanding of satellite surface asymmetries; and - a preparation and complement to the future infrared data from the Cassini probe.