J/A+A/622/A26       Molecular ion abundances in diffuse ISM       (Gerin+, 2019)

Molecular ion abundances in the diffuse ISM : CF+, HCO+, HOC+, and C3H+. Gerin M., Liszt H., Neufeld D., Godard B., Sonnentrucker P., Pety J., Roueff E. <Astron. Astrophys. 622, A26 (2019)> =2019A&A...622A..26G 2019A&A...622A..26G (SIMBAD/NED BibCode)
ADC_Keywords: Interferometry; Interstellar medium; Diffuse clouds; H II regions; Spectra, millimetric/submm Keywords: ISM: general - ISM: clouds - ISM: molecules - radio lines: ISM Abstract: The transition between atomic and molecular hydrogen is associated with important changes in the structure of interstellar clouds, and marks the beginning of interstellar chemistry. Most molecular ions are rapidly formed (in ion-molecule reactions) and destroyed (by dissociative recombination) in the diffuse ISM. Because of the relatively simple networks controlling their abundances, molecular ions are usually good probes of the underlying physical conditions including for instance the fraction of gas in molecular form or the fractional ionization. In this paper we focus on three possible probes of the molecular hydrogen column density, HCO+, HOC+, and CF+. We presented high sensitivity ALMA absorption data toward a sample of compact HII regions and bright QSOs with prominent foreground absorption, in the ground state transitions of the molecular ions HCO+, HOC+, and CF+ and the neutral species HCN and HNC, and from the excited state transitions of C3H+(4-3) and 13CS(2-1). These data are compared with Herschel absorption spectra of the ground state transition of HF and p-H2O. We show that the HCO+, HOC+, and CF+ column densities are well correlated with each other. HCO+ and HOC+ are tightly correlated with p-H2O, while they exhibit a different correlation pattern with HF depending on whether the absorbing matter is located in the Galactic disk or in the central molecular zone. We report new detections of C3H+ confirming that this ion is ubiquitous in the diffuse matter, with an abundance relative to H2 of ∼7x10-11. We confirm that the CF+ abundance is lower than predicted by simple chemical models and propose that the rate of the main formation reaction is lower by a factor of about 3 than usually assumed. In the absence of CH or HF data, we recommend to use the ground state transitions of HCO+, CCH, and HOC+ to trace diffuse molecular hydrogen, with mean abundances relative to H2 of 3x10-9, 4x10-8 and 4x10-11 respectively, leading to sensitivity N(H2)/∫τdv of 4x1020, 1.5x1021, and 6x1022cm-2/km/s, respectively. Description: The observations have been obtained with ALMA during its cycle 2. The bandpass calibrators were J1427-4206, J1717-3342, J1924-2914, and the phase calibrator was J1752-2956. As flux calibrator the solar system objects Titan, Venus, and Ceres were used. The data were calibrated and deconvolved using CASA and the resulting data-cubes were then exported to GILDAS for further analysis. The individual files are labelled according to the source and molecule observed. Each file is labelled with the source name and the molecule. C3H for C3H, CFP for CF+, HCN for HCN, HNC for HNC, 13CS for 13CS, C3HP for C3H+, HCOP for HCO+, HOCP for HOC+, It has a brief header containing ancillary information, followed by the continuum divided spectrum, listed as LSRK velocity in the first column in km/s and the variable (line/continuum-1) in the second column. The first line provides the format of the coordinates, and the units. TC is to be interpreted as the continuum flux in Jy Frequency is the doppler-shifted rest frequency of the line observed in the first channel. For example the first lines of the file SGRSHCOP.TXT containing the spectrum of HCO+ toward the southern position near SgrB2-S are as follows: RA:hh.mmssss; Dec:dd.mmsss; L,B: decimal deg.; TC: Jy; Frequency: MHz SOURCE = 'SgrS-HCO^+ ' RA = 17.472046404 DEC = -28.23448380 L = 0.6562967426 B = -0.042985450 TC = 0.6156601138 Frequency = 89135.437743 File Summary: -------------------------------------------------------------------------------- FileName Lrecl Records Explanations -------------------------------------------------------------------------------- ReadMe 80 . This file sources.dat 144 60 List of spectra sp/* . 60 Individual spectra -------------------------------------------------------------------------------- Byte-by-byte Description of file: sources.dat -------------------------------------------------------------------------------- Bytes Format Units Label Explanations -------------------------------------------------------------------------------- 1- 15 A15 --- Source Source designation 17- 18 I2 h RAh Right ascension (J2000) 20- 21 I2 min RAm Right ascension (J2000) 23- 30 F8.5 s RAs Right ascension (J2000) 32 A1 --- DE- Declination sign (J2000) 33- 34 I2 deg DEd Declination (J2000) 36- 37 I2 arcmin DEm Declination (J2000) 39- 45 F7.4 arcsec DEs Declination (J2000) 47- 60 F14.10 deg GLON Galactic longitude 62- 73 F12.9 deg GLAT Galactic longitude 75- 87 F13.11 Jy TC Continuum flux 88-100 F13.6 MHz Freq Doppler-shifted rest Frequency of the line observed in the first channel 102-115 A14 --- FileName Name of the file with spectrum in subdirectory sp 117-136 A20 --- Name Name of the QSO or HII region 137-144 A8 --- Mol Observed molecule -------------------------------------------------------------------------------- Byte-by-byte Description of file (#): sp/* -------------------------------------------------------------------------------- Bytes Format Units Label Explanations -------------------------------------------------------------------------------- 1- 19 E19.10 km/s VLSR LSRK velocity 20- 34 E15.12 --- I/Ic-1 Intensity, normalized to continuum, minus 1 (I/Ic-1) -------------------------------------------------------------------------------- Acknowledgements: Maryvonne Gerin, maryvonne.gerin(at)lra.ens.fr
(End) Patricia Vannier [CDS] 05-Nov-2018
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