J/ApJS/211/28        High resolution EUV spectrum of N2        (Heays+, 2014)

The high-resolution extreme-ultraviolet spectrum of N2 by electron impact. Heays A.N., Ajello J.M., Aguilar A., Lewis B.R., Gibson S.T. <Astrophys. J. Suppl. Ser., 211, 28 (2014)> =2014ApJS..211...28H 2014ApJS..211...28H
ADC_Keywords: Atomic physics ; Spectra, ultraviolet ; Line Profiles Keywords: line: identification; minor planets, asteroids: individual: Titan; molecular data; planets and satellites: atmospheres; radiation mechanisms: non-thermal; ultraviolet: general Abstract: We have analyzed high-resolution (FWHM=0.2Å) extreme-ultraviolet (EUV, 800-1350Å) laboratory emission spectra of molecular nitrogen excited by an electron impact at 20 and 100eV under (mostly) optically thin, single-scattering experimental conditions. A total of 491 emission features were observed from N2 electronic-vibrational transitions and atomic N I and N II multiplets and their emission cross sections were measured. Molecular emission was observed at vibrationally excited ground-state levels as high as v"=17, from the a1Πg, b1Πu, and b'1Σu+ excited valence states and the Rydberg series c'n+11Σu+, cn1Πu, and on1Πu for n between 3 and 9. The frequently blended molecular emission bands were disentangled with the aid of a sophisticated and predictive quantum-mechanical model of excited states that includes the strong coupling between valence and Rydberg electronic states and the effects of predissociation. Improved model parameters describing electronic transition moments were obtained from the experiment and allowed for a reliable prediction of the vibrationally summed electronic emission cross section, including an extrapolation to unobserved emission bands and those that are optically thick in the experimental spectra. Vibrationally dependent electronic excitation functions were inferred from a comparison of emission features following 20 and 100eV electron-impact collisional excitation. The electron-impact-induced fluorescence measurements are compared with Cassini Ultraviolet Imaging Spectrograph observations of emissions from Titan's upper atmosphere. Description: We have performed an absolutely calibrated high-resolution study of the EUV emission spectrum of molecular nitrogen between 850 and 1150Å following electron excitation. Emission spectra were recorded for low- and high-pressure N2 targets using an EUV spectrometer, with 20 and 100eV impact energies. Nearly all of the observed molecular bands are optically thin and correspond to single-scattering events. File Summary: -------------------------------------------------------------------------------- FileName Lrecl Records Explanations -------------------------------------------------------------------------------- ReadMe 80 . This file table1.dat 73 538 Experimental results -------------------------------------------------------------------------------- See also: J/A+A/559/A114 : O3N2 and N2 abundance indicators revisited (Marino+, 2013) J/A+A/439/387 : Absolute photoionization cross sections (Bizau+, 2005) J/A+AS/128/361 : Vacuum ultraviolet emission band systems of N2 (Roncin+ 1998) Byte-by-byte Description of file: table1.dat -------------------------------------------------------------------------------- Bytes Format Units Label Explanations -------------------------------------------------------------------------------- 1- 29 A29 --- Line Assignment 31- 38 F8.3 0.1nm lambda [806/1347] Peak wavelength; in Angstroms 40- 45 F6.3 10-20cm2 CS20 [0.01/51.6]? Emission cross section at 20eV 47- 51 F5.3 10-20cm2 e_CS20 [0.009/0.9]? One sigma uncertainty in CS20 53- 55 A3 --- n_CS20 Note(s) on CS20 (1) 57- 63 F7.3 10-20cm2 CS100 [0.05/178]? Emission cross section at 100eV 65- 69 F5.3 10-20cm2 e_CS100 [0.02/4]? One sigma uncertainty in CS100 71- 73 A3 --- n_CS100 Note(s) on CS100 (1) -------------------------------------------------------------------------------- Note (1): Note as follows: 1 = Line-by-line model. 2 = Significantly self-absorbed. 3 = Enhanced because of self absorption of c'4(0,0). 4 = Intensity is calculated from a direct integration and not a modelled band profile. 5 = To allow for the fitting of overlapping features the intensity of this band was assumed. -------------------------------------------------------------------------------- History: From electronic version of the journal
(End) Greg Schwarz [AAS], Emmanuelle Perret [CDS] 07-May-2014
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